WebA series of alkene-functional polymers were synthesized by controlled polymerization techniques in order to investigate and compare the efficiency and orthogonality of both photochemically and thermally initiated thiol−ene click coupling reactions. The copolymers were designed to have single or multiple alkene-functional groups along the backbone, … WebFeb 15, 2016 · Thiol–ene polymers typically contain matching numbers of thiol and ene groups. Previously, Tommy Haraldsson and colleagues, from KTH Royal Institute of Technology, found that using an excess of ...
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WebApr 1, 2024 · Triallylated l-glutamic acid and l-tyrosine (A3E amd A3Y) and their tetraallyl derivatives (A4E and A4Y) were synthesized by reactions of l-glutamic acid and l-tyrosine with allyl bromide in the presence of potassium carbonate, respectively.Thiol-ene photopolymerizations of the allylated amino acids and a pentaerythritol-based tetrathiol … WebDec 28, 2024 · The first studies on degradation of the thiol-ene polymers have been performed in the group of C.N. Bowman. For example, degradable thiol-acrylate photopolymers have been studied in . They form a new class of biomaterials, special feature of which is fast polymerization under physiological conditions under UV light, in the … homer with headphones
Off-stoichiometry thiol-ene polymer - Wikipedia
WebPolymer Chemistry. Customized thermoplastic polyhydroxyurethanes synthesized from ene-containing cyclic carbonate, dithiol and diamine: Design, mechanical property and application in adhesive ... Three types of bicyclic carbonates have been synthesized by thiol-ene coupling of ene-containing cyclic carbonate and dithiols. Then a series of ... WebOct 1, 2024 · This study presents the first report of VAM-printed thiol-ene resins. With well-ordered molecular networks, thiol-ene chemistry accesses polymer materials with a wide … WebFeb 11, 2015 · Air-stable primary phosphines were photopolymerized using phosphane–ene chemistry, the phosphorus analogue of the thiol–ene reaction, to fabricate a completely new class of polymer networks. It was demonstrated that the tunable thermal and physical properties accessible using thiol–ene chemistry could also be achieved using an … homer wing